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What Is Hastelloy? Definition, Grades (C276, C22), Properties

Time:2026-07-05

Hastelloy is a registered trademark of Haynes International designating a family of high-performance nickel-based superalloys engineered to resist severe corrosion, oxidation, and mechanical degradation in environments where stainless steels, duplex alloys, and standard nickel grades fail, with the most widely specified grades being Hastelloy C276 (UNS N10276) and Hastelloy C22 (UNS N06022), both nickel-chromium-molybdenum alloys delivering corrosion rates below 0.1 mm/year in acids, chloride solutions, and mixed industrial process streams that destroy conventional engineering metals within months. At MWalloys, we supply Hastelloy in plate, sheet, bar, pipe, tube, fittings, and wire to chemical plants, pharmaceutical manufacturers, offshore platforms, and power generation facilities globally.

Understanding what Hastelloy is, how its different grades perform, and when to specify it over competing materials requires more than reading a datasheet. It requires knowing the metallurgical reasons behind each grade's strengths and limitations, the environments where the premium cost is genuinely justified, and the fabrication practices that preserve its corrosion resistance through the manufacturing process. This article provides that complete picture.

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What Is Hastelloy and Who Produces It Commercially?

Hastelloy is a proprietary alloy family name owned by Haynes International, Inc., headquartered in Kokomo, Indiana, USA. The name itself does not describe a single alloy: it covers a broad range of nickel-based compositions unified by their design objective of providing superior resistance to corrosion and high-temperature degradation beyond what iron-based alloys can achieve.

In practical engineering usage, "Hastelloy" has become a semi-generic term that engineers apply to any nickel-chromium-molybdenum corrosion-resistant alloy of similar composition, even when the material is not produced by Haynes International. This parallels how "Inconel" (a Special Metals trademark) is used semi-generically for nickel-chromium alloys. The correct technical approach is to specify both the trade name and the UNS (Unified Numbering System) designation to prevent ambiguity during procurement.

Hastelloy Round Bar
Hastelloy Round Bar

Who Manufactures Hastelloy Alloys?

While Haynes International holds the Hastelloy trademark, the equivalent compositions defined by UNS numbers are produced by multiple qualified mills worldwide:

Manufacturer Country Key Brands / Designations
Haynes International USA Hastelloy (original trademark holder)
Special Metals Corporation USA Corronel, related Ni alloys
VDM Metals (Thyssenkrupp) Germany Nicrofer grades
Sandvik Sweden Sanicro grades
Nippon Yakin Kogyo Japan NI alloy equivalents
Outokumpu Finland Nickel alloy equivalents
Baosteel / Jiuquan China N10276, N06022 equivalents

At MWalloys, we source from both Western original mills and qualified alternative producers, verifying compliance through full chemical analysis and corrosion testing on each incoming heat. The UNS designation (N10276 for C276, N06022 for C22) is our primary quality control anchor regardless of the producing mill.

The Naming Convention Behind Hastelloy Designations

Hastelloy grades are identified by letter-number combinations that reflect their development sequence rather than their composition:

  • B series (B, B2, B3): Nickel-molybdenum alloys optimized for reducing acid resistance.
  • C series (C, C276, C22, C2000, C4): Nickel-chromium-molybdenum alloys for broad corrosion resistance.
  • G series (G, G3, G30): Nickel-chromium-molybdenum-copper alloys for phosphoric and sulfuric acid.
  • N series (N): Nickel-molybdenum-chromium for molten salt and nuclear service.
  • W series (W): Nickel-chromium-molybdenum-tungsten for welding applications.
  • X series (X): Nickel-chromium-iron-molybdenum for high-temperature oxidation resistance.

The "C" in C276 and C22 stands for the C-family chemistry base, not for any specific element. The numbers 276 and 22 are sequential development identifiers assigned during Haynes International's research program.

What Is the History and Development of Hastelloy Alloys?

The Hastelloy family has a history spanning nearly a century, driven by industrial demand for materials that could survive increasingly aggressive chemical process environments.

Timeline of Key Hastelloy Developments

Year Development Significance
1926 Original Hastelloy A (Ni-Mo) First commercial nickel-molybdenum corrosion alloy
1930s Hastelloy B introduced Improved HCl resistance; first widely adopted grade
1930s Hastelloy C introduced First Ni-Cr-Mo alloy; broad corrosion resistance
1960s Hastelloy C276 developed Reduced C and Si to solve weld sensitization of original C
1970s Hastelloy B2 developed Low iron B-series; improved reducing acid performance
1973 Hastelloy G introduced Ni-Cr-Mo-Cu for phosphoric and sulfuric acid
1980s Hastelloy C22 developed Higher Cr than C276; better oxidizing acid resistance
1989 Hastelloy C4 introduced High-temperature C-family grade
1990s Hastelloy C2000 developed Highest-PREN C-family; broadest single-grade coverage
1990s Hastelloy B3 developed Improved B-family with thermal stability and fabricability
2000s Hastelloy G35 introduced High Cr variant for oxidizing acid
2010s Continued refinement Improved cleanness, tighter composition control

The development from original Hastelloy C to C276 illustrates a recurring theme in alloy development: identifying field failure modes and eliminating their root cause through composition adjustment. Original Hastelloy C had excellent corrosion resistance in the base metal but suffered intergranular corrosion in heat-affected zones after welding, caused by carbide and silicide precipitation during cooling. C276 solved this by reducing carbon to 0.010% maximum and silicon to 0.08% maximum, essentially eliminating the precipitate-forming elements while maintaining the nickel-chromium-molybdenum base chemistry.

The subsequent development of C22 followed the same pattern: C276 performed inadequately in oxidizing acid environments encountered in flue gas desulfurization systems and pharmaceutical cleaning protocols. Raising chromium from 15.5% to 21% while adjusting molybdenum downward produced C22, which handles mixed and oxidizing environments that exceed C276's capability.

MWalloys Hastelloy C276 Wires
MWalloys Hastelloy C276 Wires

What Are the Main Hastelloy Grades and Their UNS Designations?

The Hastelloy family encompasses more grades than most engineers realize. The following table covers all commercially significant grades with their UNS numbers, compositional families, and primary applications.

Complete Hastelloy Grade Reference Table

Grade UNS Number Alloy Family Primary Alloying Key Application
Hastelloy B N10001 Ni-Mo Mo 28% Early reducing acid grade (largely replaced)
Hastelloy B2 N10665 Ni-Mo Mo 28%, low Fe Concentrated HCl, reducing acids
Hastelloy B3 N10675 Ni-Mo Mo 28.5%, low Cr Improved B-series; reducing acids, better thermal stability
Hastelloy C N10002 Ni-Cr-Mo Cr 15.5%, Mo 17% Original C-family (sensitization issues; largely obsolete)
Hastelloy C4 N06455 Ni-Cr-Mo Cr 16%, Mo 16%, Ti High-temperature stability version of C-family
Hastelloy C276 N10276 Ni-Cr-Mo-W Cr 15.5%, Mo 16%, W 3.75% Most widely used CRA; reducing and mixed environments
Hastelloy C22 N06022 Ni-Cr-Mo-W Cr 21%, Mo 13.5%, W 3% Mixed and oxidizing acid environments
Hastelloy C2000 N06200 Ni-Cr-Mo-Cu Cr 23%, Mo 16%, Cu 1.6% Broadest single-alloy corrosion coverage
Hastelloy G N06007 Ni-Cr-Mo-Cu Cr 22%, Mo 6.5%, Cu 2% Phosphoric and sulfuric acid
Hastelloy G3 N06985 Ni-Cr-Mo-Cu Cr 22%, Mo 7%, Cu 2% Improved G series
Hastelloy G30 N06030 Ni-Cr-Mo-Cu Cr 30%, Mo 5%, Cu 2% High oxidizing acid; phosphoric acid
Hastelloy G35 N06035 Ni-Cr-Mo Cr 33.2%, Mo 8.1% Highly oxidizing environments
Hastelloy N N10003 Ni-Mo-Cr Mo 16%, Cr 7% Molten salt; nuclear reactor service
Hastelloy W N10004 Ni-Mo-Cr Mo 24.5%, Cr 5% Welding filler metal (obsolete as base metal)
Hastelloy X N06002 Ni-Cr-Fe-Mo Cr 22%, Fe 18%, Mo 9% High-temperature oxidation; gas turbines
Hastelloy S N06635 Ni-Cr-Mo Cr 15.5%, Mo 14.5% High-temperature oxidation + moderate corrosion

Which Hastelloy Grades Are Most Commonly Specified in 2026?

Based on procurement patterns at MWalloys across chemical processing, offshore energy, pharmaceutical, and power generation markets in 2026:

Rank Grade Market Share (Approx.) Primary Driving Industry
1 C276 ~45% of Hastelloy volume Chemical processing, oil/gas
2 C22 ~30% of Hastelloy volume FGD, pharma, nuclear
3 B3 ~8% of Hastelloy volume HCl and reducing acid plants
4 X ~6% of Hastelloy volume Aerospace, gas turbine
5 C2000 ~4% of Hastelloy volume Most aggressive mixed environments
6 G30 ~3% of Hastelloy volume Phosphoric acid production
7 Others ~4% Specialty applications

C276 and C22 together account for approximately 75% of all Hastelloy consumed globally, which is why this article focuses most of its technical depth on these two grades.

What Are the Chemical Compositions of Key Hastelloy Grades?

Chemical composition is the foundation of Hastelloy performance. The following detailed tables cover the grades most relevant to engineering specification work.

C276 vs C22 Detailed Composition Comparison

Element Hastelloy C276 (N10276) Min/Max (%) Hastelloy C22 (N06022) Min/Max (%) Role in Corrosion Performance
Nickel (Ni) Balance (~57%) Balance (~56%) Base matrix; SCC immunity; electrochemical stability
Chromium (Cr) 14.5 / 16.5 20.0 / 22.5 Passive film stability; oxidizing acid resistance
Molybdenum (Mo) 15.0 / 17.0 12.5 / 14.5 Reducing acid resistance; pitting resistance
Tungsten (W) 3.0 / 4.5 2.5 / 3.5 Synergistic pitting + crevice resistance
Iron (Fe) 4.0 / 7.0 2.0 / 6.0 Controlled residual
Cobalt (Co) Max 2.5 Max 2.5 Controlled residual
Carbon (C) Max 0.010 Max 0.010 Minimized: prevents HAZ carbide sensitization
Silicon (Si) Max 0.08 Max 0.08 Minimized: prevents silicide precipitation
Manganese (Mn) Max 1.0 Max 0.50 Deoxidation
Phosphorus (P) Max 0.025 Max 0.025 Impurity control
Sulfur (S) Max 0.010 Max 0.010 Impurity control; hot ductility
Vanadium (V) Max 0.35 – Minor residual in C276

Hastelloy B3, C2000, X and G30 Compositions

Element B3 (N10675) C2000 (N06200) X (N06002) G30 (N06030)
Nickel (Ni) Balance (~65%) Balance (~59%) Balance (~47%) Balance (~43%)
Chromium (Cr) 1.0 – 3.0% 22.0 – 24.0% 20.5 – 23.0% 28.0 – 31.5%
Molybdenum (Mo) 27.0 – 32.0% 15.0 – 17.0% 8.0 – 10.0% 4.0 – 6.0%
Tungsten (W) 3.0% max – 0.2 – 1.0% 1.5 – 4.0%
Iron (Fe) 1.0 – 3.0% 3.0% max 17.0 – 20.0% 13.0 – 17.0%
Copper (Cu) – 1.3 – 1.9% – 1.0 – 2.4%
Cobalt (Co) 3.0% max 2.0% max 0.5 – 2.5% 5.0% max
Carbon (C) 0.010% max 0.010% max 0.05 – 0.15% 0.03% max
Silicon (Si) 0.10% max 0.08% max 0.50 – 1.0% 1.0% max

The compositional difference between Hastelloy B3 and the C-family is dramatic. B3 is essentially a nickel-molybdenum binary alloy with minimal chromium, optimized purely for reducing acid resistance. Adding chromium would improve oxidizing acid resistance but simultaneously reduce reducing acid performance because chromium raises the alloy's electrode potential toward the transpassive range in reducing media. B3 is the correct choice when the service environment is exclusively reducing and no oxidizing species are present or can enter the system during upsets or cleaning.

What Mechanical and Physical Properties Do Hastelloy Alloys Deliver?

Hastelloy alloys are not selected purely for corrosion resistance. Their mechanical properties must be adequate for the structural requirements of the application, and understanding these properties is essential for pressure vessel design and structural calculations.

Room Temperature Mechanical Properties Comparison

Property C276 C22 B3 X G30 Test Standard
Tensile Strength (MPa) 790 min 690 min 760 min 655 min 690 min ASTM E8
Yield Strength (MPa, 0.2%) 355 min 310 min 345 min 255 min 310 min ASTM E8
Elongation (%) 40 min 45 min 40 min 35 min 40 min ASTM E8
Hardness (Rockwell B) ~90 ~85 ~88 ~85 ~85 ASTM E18
Charpy Impact (J, RT) ~100 ~110 ~95 ~90 ~100 ASTM E23

Elevated Temperature Strength Retention for C276 and C22

Temperature (°C) C276 Tensile (MPa) C276 Yield (MPa) C22 Tensile (MPa) C22 Yield (MPa)
20 790 355 690 310
100 740 310 660 280
200 700 285 630 260
300 670 270 610 250
400 650 260 595 240
500 620 250 570 230
600 580 240 540 220
700 510 230 480 210
800 380 200 360 185

Physical Properties of Key Hastelloy Grades

Physical Property C276 C22 B3 X
Density (g/cm³) 8.89 8.69 9.22 8.22
Melting range (°C) 1325 – 1370 1357 – 1399 1370 – 1418 1260 – 1355
Thermal conductivity (W/m·K, 20°C) 10.2 10.1 11.1 11.3
Modulus of elasticity (GPa) 205 211 219 205
Coefficient of thermal expansion (µm/m·°C) 11.2 12.7 10.6 13.3
Electrical resistivity (µΩ·m) 1.30 1.14 1.37 1.18
Magnetic permeability < 1.002 < 1.002 < 1.002 < 1.002

The non-magnetic character of all Hastelloy grades (permeability below 1.002) is a practically important property for applications near magnetic compasses, MWD (measurement-while-drilling) tools, MRI equipment, and degaussed naval vessels. All Hastelloy C-family and B-family alloys are austenitic in structure and remain non-magnetic in all service conditions.

How Does Hastelloy Resist Corrosion and What Environments Can It Handle?

The corrosion resistance of Hastelloy alloys operates through the same passive film mechanism as stainless steel, but with a more stable and self-repairing passive oxide layer enabled by the high nickel base and the synergistic effects of chromium, molybdenum, and tungsten.

The Passive Film Mechanism in Hastelloy

When Hastelloy is exposed to an oxidizing or aqueous environment, chromium in the alloy reacts with oxygen to form a thin (2 – 5 nanometer) chromium oxide (Cr₂O₃) passive layer. The key differences between this film and the equivalent film on stainless steel are:

  • Greater stability range: The high nickel content shifts the alloy's electrode potential, widening the potential window over which the passive film is thermodynamically stable.
  • Molybdenum enhancement: Molybdenum enriches the passive film at the metal-oxide interface, reducing the ionic conductivity of the film and slowing corrosion current even when local film defects occur.
  • Tungsten synergy: Tungsten interacts with molybdenum at pit initiation sites, disrupting the electrochemical processes that propagate pits before they can grow.
  • Self-repair: Film damage is repaired within milliseconds in oxygen-containing environments because the driving force for chromium oxidation is strong at all normal operating conditions.

Corrosion Rate Data Across Key Environments

Environment 316L SS Duplex 2507 C276 C22 C2000
65% HNO₃, boiling Fails rapidly Fails 19.1 mpy 2.1 mpy 1.8 mpy
10% HCl, 70°C Fails Fails 5.8 mpy 7.3 mpy 6.5 mpy
20% Hâ‚‚SOâ‚„, boiling Fails Fails 9.5 mpy 11.2 mpy 8.9 mpy
FeCl₃ (10%), 50°C Fails rapidly Moderate 4.2 mpy 1.1 mpy 0.8 mpy
Seawater (ambient) Pitting No pitting No pitting No pitting No pitting
Hâ‚‚S sour service SCC risk Acceptable Excellent Excellent Excellent
10% HNO₃ + 2% HF Fails Fails 35.4 mpy 8.7 mpy 7.2 mpy
Acetic acid (glacial) Acceptable Good Excellent Excellent Excellent

mpy = mils per year. Values approximate from published test data; exact conditions vary by source.

Pitting Resistance Equivalent Number (PREN) for Hastelloy Grades

PREN = %Cr + 3.3 × (%Mo + 0.5 × %W) + 16 × %N

Grade Cr (%) Mo (%) W (%) PREN (approx.) Classification
C276 15.5 16.0 3.75 ~72 Outstanding pitting resistance
C22 21.0 13.5 3.0 ~71 Outstanding pitting resistance
C2000 23.0 16.0 0 ~76 Outstanding pitting resistance
B3 1.5 28.5 3.0 ~98 Mathematical artifact; no Cr passive film
G30 30.0 5.0 2.0 ~50 Very Good
X 22.0 9.0 0.5 ~54 Very Good
316L (reference) 17.0 2.2 0 ~24 Moderate
Super duplex 2507 (ref) 25.0 4.0 0 ~42 Good

Note: The B3 PREN value is mathematically high due to extreme molybdenum content but is not meaningful in the standard PREN context because B3's near-zero chromium content means it does not form a chromium-based passive film. Its corrosion resistance in reducing acids operates through a completely different mechanism.

Types of Corrosion That Hastelloy Resists

Corrosion Type C276 Resistance C22 Resistance Notes
Uniform (general) corrosion Excellent Excellent Both alloys superior in most acids
Pitting corrosion (chloride) Excellent Excellent PREN ~70 for both
Crevice corrosion Very Good Excellent C22 advantage at elevated temperature
Stress corrosion cracking Excellent Excellent Ni content > 40% provides immunity
Intergranular corrosion Very Good Very Good Low C prevents sensitization
Galvanic corrosion Noble behavior Noble behavior Both are noble; protect coupled metals
Erosion-corrosion Good Good Better than SS but not best for abrasion
Microbiologically influenced corrosion Very Good Very Good Ni alloys resist MIC better than SS

How Do Hastelloy C276 and C22 Differ When It Comes to Real Industrial Applications?

The C276 vs C22 selection question is the most frequently asked Hastelloy topic we encounter at MWalloys. The answer is nuanced and depends heavily on the specific corrosive environment.

Hastelloy C276 vs C22 comparison infographic showing corrosion resistance, industrial applications, and key performance differences for chemical processing alloys.
Hastelloy C276 vs C22 comparison infographic showing corrosion resistance, industrial applications, and key performance differences for chemical processing alloys.

The Fundamental Composition-Performance Relationship

The core difference between C276 and C22 reduces to a trade-off between chromium and molybdenum:

  • C276 prioritizes molybdenum (16% Mo, 15.5% Cr): Superior in reducing acids where molybdenum's electrochemical effect dominates.
  • C22 prioritizes chromium (21% Cr, 13.5% Mo): Superior in oxidizing environments where chromium passive film stability dominates.

Neither alloy is universally superior. The correct selection requires a genuine characterization of the process environment's oxidizing/reducing character.

Side-by-Side Application Performance Comparison

Application / Environment C276 Performance C22 Performance Recommended Choice
FGD absorber tower Good (8 – 12 yr life) Excellent (18 – 25 yr life) C22
HCl acid plant Excellent Good C276
Pharmaceutical CIP (HNO₃ cycles) Moderate Excellent C22
Sulfuric acid (20%), hot Excellent Good C276
Nuclear waste (HNO₃ based) Moderate Excellent C22
Mixed acid chemical plant Moderate Excellent C22
Hâ‚‚S sour service Excellent Excellent Either (C276 slight advantage)
Pulp mill bleach plant (ClOâ‚‚) Good Excellent C22
Seawater service Excellent Excellent Either
Hydrofluoric acid Not recommended Not recommended Monel 400 instead
Phosphoric acid (wet process) Good Good Either; G-series may be better
Pesticide manufacturing Excellent Good C276

Cost Comparison and When the Upgrade Makes Financial Sense

Cost Factor C276 C22
Typical plate price premium vs 316L ~8× ~10×
C22 premium over C276 Baseline +15 – 25%
FGD service life (absorber liner) 8 – 12 years 18 – 25 years
Annualized cost (C276 at 10yr) 100% of C276/10 N/A
Annualized cost (C22 at 20yr) N/A ~60% of C276 annual cost
Payback period for C22 upgrade in FGD – First inspection cycle

The lifecycle cost analysis almost invariably favors C22 over C276 in any application that has significant oxidizing character. The additional upfront cost is recovered within the first service interval through extended equipment life and reduced maintenance shutdowns.

What Product Forms Is Hastelloy Available In, and What Are Standard Dimensions?

Hastelloy is commercially available in virtually all standard wrought product forms. Understanding which product forms are most available from stock versus requiring mill production orders affects project schedule planning.

Hastelloy product forms and standard dimensions infographic covering plates, sheets, pipes, tubes, bars, wires, fittings, and flanges.
Hastelloy product forms and standard dimensions infographic covering plates, sheets, pipes, tubes, bars, wires, fittings, and flanges.

Available Product Forms and Applicable Standards

Product Form ASTM Standard ASME Standard Typical Thickness/Diameter Range
Plate and sheet B575 SB-575 0.5mm – 100mm thick
Bar (hot rolled) B574 SB-574 6mm – 300mm diameter
Seamless pipe and tube B622 SB-622 6mm – 300mm OD
Welded pipe B619 SB-619 6mm – 600mm OD
Welded tube B626 SB-626 6mm – 150mm OD
Fittings B366 SB-366 Per ASME B16.9/B16.11
Flanges B564 (forgings) SB-564 Per ASME B16.5/B16.47
Wire B Wire (custom) – 0.05mm – 12mm
Strip and narrow coil B575 SB-575 0.1mm – 6.35mm thick
Forgings B564 SB-564 Custom shapes

Stock Availability at MWalloys

At MWalloys, we maintain strategic inventory in the highest-demand Hastelloy C276 and C22 product forms to support urgent project requirements:

Product Form Stocked Grades Standard Sizes Lead Time (from stock)
Plate (C276) N10276 3 – 75mm thick, various widths 1 – 5 business days
Plate (C22) N06022 3 – 50mm thick, various widths 1 – 5 business days
Seamless pipe (C276) N10276 1/4" – 8" NPS 3 – 10 business days
Seamless pipe (C22) N06022 1/4" – 6" NPS 3 – 10 business days
Bar (C276) N10276 6mm – 150mm diameter 3 – 7 business days
Bar (C22) N06022 6mm – 100mm diameter 3 – 7 business days
Fittings (C276) N10276 1/4" – 8" 1 – 5 business days
Welding wire (C22) ERNiCrMo-10 1.6mm, 2.4mm straight 1 – 5 business days

How Is Hastelloy Correctly Fabricated, Welded, and Machined?

Fabrication of Hastelloy requires techniques and precautions that differ significantly from carbon steel and even austenitic stainless steel practice. Errors at the fabrication stage can permanently compromise corrosion resistance.

Welding Hastelloy Alloys

Welding is the most critical fabrication operation for corrosion-resistant performance. The following table covers the key parameters for C276 and C22:

Welding Parameter C276 C22 General Rule
Matching filler (GTAW) ERNiCrMo-4 ERNiCrMo-10 Match or upgrade filler
Cross-compatible filler ERNiCrMo-10 can weld C276 ERNiCrMo-10 C22 filler upgrades C276 welds
Shielding gas 100% Ar 100% Ar No active gas additions
Back purge 100% Ar (Oâ‚‚ < 50 ppm) 100% Ar Essential for root pass
Preheat Not required < 25mm Not required < 25mm Avoid: promotes sensitization
Interpass temperature < 150°C < 150°C Critical limit
Post-weld heat treatment Not required (most applications) Not required PWHT rarely needed
Post-weld surface treatment Mandatory: pickling or electroclean Mandatory Removes heat tint

The Critical Importance of Post-Weld Heat Tint Removal

One of the most consequential and most overlooked fabrication steps is removal of the heat tint (the discolored oxidized zone) from the plate surface adjacent to welds. This chromium-depleted zone can be 5 – 10 times less corrosion resistant than the parent metal, making it the first area to corrode in service.

Method Effectiveness Procedure
HNO₃ + HF pickling Excellent 10% HNO₃ + 2% HF; 15 – 30 min; rinse; passivate
Electrochemical cleaning Very Good Citric or phosphoric acid electrolyte; portable equipment
Glass bead blast + passivation Good Dedicated non-iron media; no carryover from steel blasting
Stainless wire brush + passivation Acceptable Dedicated SS brush only; never carbon steel brush

Critical contamination rules:

  • Never use grinding wheels, wire brushes, or abrasives previously used on carbon steel.
  • Never use chloride-containing cutting fluids or lubricants.
  • Never allow sulfur-bearing compounds to contact Hastelloy at any temperature.
  • Always use dedicated tooling that has not contacted iron-containing materials.

Machining Hastelloy

Hastelloy's machinability rating (approximately 20 – 30% of B1112 free-machining steel) reflects its strong work-hardening tendency and high strength. Successful machining requires:

Machining Factor Requirement Consequence of Non-Compliance
Cutting speed 15 – 30 m/min (turning) Too high: rapid tool wear; galling
Feed rate 0.15 – 0.30 mm/rev Too low: rubbing and work hardening
Tool material Carbide mandatory; coated preferred HSS acceptable only for light finishing
Coolant Sulfur-free synthetic flood coolant Sulfur causes intergranular attack
Tool path Continuous cut; no dwelling Dwelling causes work hardening and tool damage
Depth of cut 2 – 4mm roughing; 0.5mm finishing Shallow cuts cause rubbing

Forming and Heat Treatment

Cold forming of Hastelloy in the annealed condition is feasible but requires increased forming forces due to higher yield strength compared to mild steel. After any hot forming operation above 900°C, a full solution anneal (minimum 1121°C followed by rapid quench) must be performed before the component enters corrosive service.

The sensitization temperature range (500 – 900°C) must never be used for stress relief. Conventional stress relief in this range causes precipitation of chromium-depleted intermetallic phases that destroy corrosion resistance. The only acceptable thermal treatment for restoring full properties is full solution annealing.

What Standards and Specifications Govern Hastelloy Alloys in Pressure Vessel and Industrial Applications?

Primary Standards Reference Table

Standard Body Scope Key Hastelloy Grades Covered
ASTM B575 ASTM Plate, sheet, strip C276 (N10276), C22 (N06022), B3, C2000
ASTM B574 ASTM Bar, rod C276, C22, B3, C2000, G30
ASTM B622 ASTM Seamless pipe and tube C276, C22, B3, G30
ASTM B619 ASTM Welded pipe C276, C22
ASTM B626 ASTM Welded tube C276, C22
ASTM B366 ASTM Pipe fittings C276 (WPHC276), C22 (WPHC22)
ASTM B564 ASTM Forgings C276, C22
ASME SB-575 ASME Plate (pressure vessel) Same as B575, ASME Code approved
ASME SB-622 ASME Pipe (pressure vessel) Same as B622, ASME Code approved
NACE MR0175 / ISO 15156 AMPP/ISO Sour service C276, C22 qualified with conditions
AWS A5.14 AWS Welding wire ERNiCrMo-4 (C276), ERNiCrMo-10 (C22)
EN 10095 CEN High-temp alloy sheet European equivalents

ASME Allowable Stresses for C276 and C22

Temperature (°C) C276 Allowable Stress (MPa) C22 Allowable Stress (MPa)
40 (ambient) 148 138
100 140 132
200 132 123
300 127 117
400 123 113
500 118 103
538 108 90

These values from ASME Section II Part D are used directly in pressure vessel wall thickness calculations. C276 shows slightly higher allowable stresses than C22 at all temperatures due to its higher molybdenum content providing additional solid solution strengthening.

How Does Hastelloy Compare to Inconel, Monel, and Stainless Steel in Engineering Selection?

Comprehensive Alloy Family Comparison

Property Hastelloy C276 Hastelloy C22 Inconel 625 Monel 400 316L SS Duplex 2205
Base metal Nickel Nickel Nickel Nickel-Copper Iron Iron
Cr (%) 15.5 21 22 0 17 22
Mo (%) 16 13.5 9 0 2.2 3
PREN ~72 ~71 ~52 N/A ~24 ~35
Oxidizing acid resistance Moderate Excellent Good Poor Limited Limited
Reducing acid resistance Excellent Good Moderate Good Limited Limited
Seawater pitting Excellent Excellent Excellent Excellent Poor Good
Chloride SCC resistance Excellent Excellent Excellent Excellent Poor above 60°C Good
HF acid resistance Poor Poor Poor Excellent Poor Poor
Max service temp (°C) 1038 (oxidizing atm) 1038 982 450 870 300
NACE MR0175 Yes Yes Yes Yes (with conditions) Limited Yes
Relative cost ~8× 316L ~10× 316L ~9× 316L ~5× 316L 1× ~2× 316L
Weldability Excellent Excellent Excellent Good Very Good Moderate

Selection Decision Framework

Choose Hastelloy C276 when:

  • The primary corrosive medium is reducing acids (HCl, dilute Hâ‚‚SOâ‚„, Hâ‚‚S)
  • Mixed environments are present but reducing character dominates.
  • Sour oil and gas service requires both Hâ‚‚S resistance and seawater immunity.
  • Budget is constrained and reducing-only environment analysis confirms adequacy.

Choose Hastelloy C22 when:

  • Any oxidizing species are present (HNO₃, FeCl₃, Clâ‚‚, Hâ‚‚Oâ‚‚, bleach)
  • The environment alternates between oxidizing and reducing conditions.
  • FGD scrubbing, pharmaceutical CIP, or nuclear waste processing is the application.
  • Maximum crevice corrosion resistance at elevated temperatures is required.

Choose Inconel 625 when:

  • Fatigue performance in seawater is the primary concern (flexible risers, bellows)
  • Weld cladding or overlay is required.
  • High strength at temperature combined with corrosion resistance is needed.
  • Niobium content adds value (weld stabilization, no post-weld heat treatment needed)

Choose Monel 400 when:

  • Hydrofluoric acid service at any concentration is involved.
  • Cost must be minimized while maintaining nickel alloy corrosion performance.
  • Seawater service without HF is the application and Monel's lower cost is attractive.

Choose 316L stainless when:

  • The environment is mild (atmospheric, fresh water, dilute acids at ambient temperature)
  • Cost is the primary driver and corrosion requirements can be met with lower-alloy material.
  • Availability and fabrication simplicity outweigh corrosion performance concerns.

FAQs: What Engineers and Procurement Professionals Ask About Hastelloy

1: Is Hastelloy the same as stainless steel?

No, Hastelloy is fundamentally different from stainless steel: Hastelloy is a nickel-based alloy (containing 56 – 70% nickel as the primary element) while stainless steel is an iron-based alloy (iron is the primary element at 60 – 75%). This distinction produces dramatically different corrosion performance, temperature capability, and cost. Stainless steel (including 316L, duplex 2205, and super duplex 2507) achieves corrosion resistance through a chromium-based passive film that becomes unstable in many reducing acids, concentrated chloride solutions, and environments combining both oxidizing and reducing species. Hastelloy's nickel-rich matrix provides greater electrochemical stability across a wider range of corrosive conditions, and the addition of molybdenum (8 – 28% depending on grade) provides reducing acid resistance that no iron-based alloy can match. The practical consequence of this difference is that Hastelloy is specified when stainless steel has already failed or when corrosion analysis predicts stainless steel will fail within an unacceptable timeframe. The cost difference (Hastelloy C276 costs approximately 8 times more per kilogram than 316L stainless) is justified by the dramatically extended service life in aggressive environments, which typically makes Hastelloy the lower-cost option over the full equipment lifecycle.

2: What is Hastelloy C276 used for?

Hastelloy C276 (UNS N10276) is primarily used in chemical processing equipment, oil and gas production hardware, pollution control systems, and pharmaceutical manufacturing where the service environment contains reducing acids such as hydrochloric acid, hydrogen sulfide, or dilute sulfuric acid combined with chloride-containing process streams that cause rapid failure of stainless steels. Specific applications include: heat exchangers in HCl service, reactor vessels in organic acid and reducing acid chemical plants, valve bodies and pump housings in sour oil and gas production, sour service downhole tubulars and completion equipment, flue gas desulfurization absorber components (though C22 is increasingly preferred in this application), pharmaceutical reactor vessels handling reducing process chemistries, and pollution control scrubbers. C276 is available in every standard product form: plate, sheet, bar, pipe, tube, fittings, flanges, and wire. ASTM B575 (plate), B574 (bar), and B622 (pipe and tube) are the primary material specifications, with ASME SB-series equivalents for pressure vessel Code construction. A key advantage of C276 is its excellent weldability using ERNiCrMo-4 filler, which allows complex fabricated assemblies to be constructed with confidence that weld joints will not become preferential corrosion sites.

3: What is the difference between Hastelloy C276 and C22?

The critical difference between Hastelloy C276 and C22 is their chromium content and resulting performance in oxidizing environments: C276 contains 15.5% chromium and excels in reducing acid service, while C22 contains 21% chromium and outperforms C276 by a factor of 5 to 10 in oxidizing acid environments and mixed acid conditions. Both alloys belong to the same nickel-chromium-molybdenum-tungsten family and look identical as metal products: the distinction is entirely in composition and resulting electrochemical behavior. In 65% boiling nitric acid (a strongly oxidizing test), C276 corrodes at approximately 19 mils/year while C22 corrodes at approximately 2 mils/year. In concentrated hydrochloric acid (a strongly reducing test), C276 performs slightly better than C22. For environments containing both oxidizing and reducing species (the majority of real industrial processes), C22 consistently demonstrates better practical performance because its higher chromium content maintains a stable passive film even when oxidizing species drive the electrochemical potential toward the transpassive range. The cost premium of C22 over C276 is typically 15 to 25%, and in most applications with any oxidizing character, this premium pays back rapidly through extended service life.

4: Can Hastelloy be used at high temperatures?

Yes, Hastelloy alloys can be used at elevated temperatures, with the operational limits depending strongly on the specific grade: Hastelloy X and Hastelloy S are specifically designed for sustained high-temperature service up to approximately 1175°C in oxidizing atmospheres, while the corrosion-optimized C-family grades (C276, C22) are generally limited to structural service below 500°C where their allowable stresses are listed in ASME Code tables. Hastelloy X (N06002) is the primary Hastelloy grade for high-temperature aerospace applications including gas turbine combustion liners, transition ducts, and industrial furnace components. Its high chromium (22%) and iron (18%) content provides excellent oxidation resistance, while molybdenum (9%) contributes solid solution strengthening at temperature. The C-family grades (C276, C22) maintain strength up to approximately 538°C per ASME Code allowable stresses, but above this range creep becomes the limiting mechanism and allowable stresses are not listed. For combined high-temperature service and corrosion resistance (such as in waste incinerators or chemical plant reactors operating above 500°C), Hastelloy X or the Inconel 600 family are generally more appropriate than the corrosion-optimized C-family grades.

5: Is Hastelloy magnetic?

No, Hastelloy alloys are non-magnetic in all normal conditions, with relative magnetic permeability below 1.002, because their high nickel content stabilizes an austenitic (face-centered cubic) crystal structure that does not support ferromagnetic domain formation. This non-magnetic character is practically important for applications near magnetic compasses (maritime navigation requires non-magnetic materials within the compass safe distance), MWD (measurement-while-drilling) tools in directional oil and gas drilling (where the tool housing must not distort geomagnetic field measurements), MRI equipment rooms (where ferromagnetic materials create safety hazards and image artifacts), and degaussed naval vessels (where magnetic signature reduction requires non-magnetic structural materials). Unlike austenitic stainless steels (304, 316L) that can develop magnetic response after cold working or at sub-zero temperatures through deformation-induced martensite formation, Hastelloy's very high nickel content (56 – 70%) makes martensite formation essentially impossible under any practical manufacturing condition or service temperature. The non-magnetic property of Hastelloy is stable regardless of cold work level, prior heat treatment history, or service temperature down to cryogenic conditions.

6: How does Hastelloy perform in hydrofluoric acid?

Hastelloy C276 and C22 are NOT recommended for use in hydrofluoric acid service: HF causes rapid attack on nickel-chromium-molybdenum alloys because fluoride ions destabilize the chromium oxide passive film that protects these materials. Monel 400 (nickel-copper alloy) and Hastelloy B3 (nickel-molybdenum alloy) are the correct choices for HF service. Monel 400 withstands HF at most concentrations because nickel and copper both form stable fluoride compounds in HF that protect the base metal. Hastelloy B3, with minimal chromium and very high molybdenum, also performs reasonably in certain HF conditions. The C-family Hastelloy grades (C276, C22, C2000) contain significant chromium (15 – 23%), which is attacked by fluoride ions, making them unsuitable for HF acid systems. This is a commonly misunderstood limitation: engineers who specify C276 for "all acids" without checking HF compatibility create equipment that fails rapidly and unexpectedly. At MWalloys, we routinely encounter specifications that incorrectly call out C276 for HF service, and our technical review process catches and corrects these errors before material is supplied. Always verify the specific acid compatibility of your chosen Hastelloy grade against the actual process chemistry.

7: What is the price of Hastelloy C276 per kilogram?

Hastelloy C276 plate prices typically range from approximately $38 to $55 USD per kilogram in mid-2026 for standard thicknesses in plate form, with significant variation based on product form, thickness, width, quantity, and market conditions. Hastelloy C22 carries a premium of approximately 15 to 25% over equivalent C276 product forms. The price structure reflects raw material costs (nickel, molybdenum, and tungsten are all significant cost drivers), the complexity of the melting process (vacuum induction melting followed by vacuum arc remelting or electroslag remelting), and the lower production volumes compared to stainless steel. Tube and pipe products are typically 20 to 40% higher per kilogram than equivalent plate, reflecting the additional manufacturing steps. Welding wire (ERNiCrMo-4 for C276, ERNiCrMo-10 for C22) carries the highest per-kilogram premium due to the drawing and packaging operations. Price comparison with stainless steel: C276 plate costs approximately 7 to 9 times more per kilogram than 316L plate of equivalent dimensions. However, lifecycle cost comparisons in corrosive service typically show Hastelloy as the lower-cost option because its dramatically longer service life (often 3 to 10 times that of stainless steel) reduces maintenance, replacement, and production-loss costs over the equipment design life.

8: Does Hastelloy require any special heat treatment?

Hastelloy C-family alloys (C276, C22, C2000) must be supplied in the solution-annealed condition (minimum 1121°C followed by rapid quench) and must not be stress relieved in the sensitization range of 500 – 900°C, which would precipitate damaging intermetallic phases and completely destroy the corrosion resistance that makes these alloys valuable. The solution anneal dissolves all precipitates into the nickel matrix, producing a single-phase austenitic microstructure with maximum corrosion resistance and optimal ductility. The rapid quench (water quench or forced air cool) prevents re-precipitation during cooling. Standard stress relief treatments used for carbon steel (typically 600 – 650°C) fall directly within the sensitization range for Hastelloy and must never be applied. After welding, no post-weld heat treatment is required for most Hastelloy applications: the very low carbon content (0.010% maximum) minimizes carbide precipitation during the weld thermal cycle, and the high nickel base provides adequate toughness in the as-welded condition. If a complete solution anneal is required after welding (for example, to homogenize the weld metal and HAZ in a critical assembly), this must be performed at the full 1121°C+ anneal temperature, not at any intermediate temperature.

9: What certifications should I require when purchasing Hastelloy?

For most industrial applications, Hastelloy material should be purchased with an EN 10204 Type 3.1 material test certificate as the minimum, which provides chemical analysis and mechanical test results certified by the manufacturer's quality control department with full heat number traceability; critical applications in pressure vessels, offshore, nuclear, or pharmaceutical service require Type 3.2 certification with independent third-party inspection witness. The Type 3.1 certificate must include: full chemical analysis confirming compliance with the UNS N10276 or N06022 composition limits, mechanical test results (tensile strength, yield strength, elongation) from the specific heat, product form (plate/pipe/bar), heat number and lot number for traceability, applicable material standard (ASTM B575/B574/B622 or ASME SB equivalents), and physical marking on the material confirming the heat number. Supplemental certifications frequently required include: NACE MR0175 / ISO 15156 compliance statement with hardness verification for sour service, ASTM G28 intergranular corrosion test results for critical corrosion service, positive material identification (PMI) results from XRF analysis, and for nuclear applications, full NQA-1 documentation package. MWalloys provides Type 3.1 certification as standard on all Hastelloy orders and Type 3.2 with advance notice for critical applications.

10: How do I know if I need Hastelloy or if a cheaper alloy will work?

The decision to specify Hastelloy should be based on a structured corrosion assessment comparing predicted corrosion rates in the actual service environment against an acceptable maximum rate (typically 0.1 mm/year for structural applications), with Hastelloy justified when lower-cost alternatives exceed this threshold or when failure consequences (safety, environmental, or production impact) make the cost premium economically rational. The assessment process begins with complete characterization of the corrosive medium: all chemical species (not just the primary acid), their concentrations under both normal and upset conditions, operating temperature range, halide ion content, pH, and whether the environment is primarily oxidizing or reducing in character. Against this environment profile, corrosion rate data from published test results (Haynes International technical bulletins, NACE publications, ASM Corrosion Handbook) provides preliminary screening. If the predicted corrosion rate for 316L or duplex stainless steel exceeds 0.5 mm/year, Hastelloy should be evaluated. If the rate for C276 exceeds 0.5 mm/year, C22, C2000, or zirconium alloys should be considered. Lifecycle cost analysis that includes equipment replacement, maintenance labor, production downtime, and consequence-of-failure costs almost always shows Hastelloy to be cost-competitive in severe corrosive service despite its high initial material cost. At MWalloys, our technical engineering team provides complimentary material selection consultation for complex corrosion cases.

Conclusion: Choosing the Right Hastelloy Grade Requires More Than a Datasheet

Hastelloy represents one of the most consequential material selection decisions in chemical plant engineering, offshore construction, pharmaceutical manufacturing, and power generation. The family's breadth, from B3's extreme reducing acid specialization to C22's mixed-environment versatility, means there is a Hastelloy grade optimized for nearly any corrosive challenge.

The critical success factors in Hastelloy selection and use:

  • Never default to C276 without assessing whether the environment has oxidizing character: C22 outperforms C276 in the majority of real industrial process environments.
  • Specify by UNS number (N10276 for C276, N06022 for C22) not just trade name.
  • Require EN 10204 Type 3.1 certification as minimum; Type 3.2 for critical applications.
  • Remove heat tint after all welding operations: this single step prevents the majority of HAZ-initiated corrosion failures.
  • Never stress relieve Hastelloy below 900°C: the sensitization range destroys corrosion resistance.
  • Use dedicated tooling free from iron contamination in all fabrication operations.
  • Base selection on lifecycle cost, not initial material price: Hastelloy almost invariably wins the economic argument in severe corrosive service.

Source Hastelloy C276, C22, and All Grades from MWalloys

MWalloys supplies the complete Hastelloy alloy family in plate, sheet, bar, pipe, tube, fittings, flanges, and wire with full EN 10204 Type 3.1 and 3.2 certifications, from ASME SB-series standards for pressure vessel construction to NACE MR0175 compliant supply for sour service applications.

Our Hastelloy supply capabilities include:

  • C276 and C22 in stock for most common product forms with same-week delivery.
  • Cut-to-size plate and sheet by waterjet, bandsaw, or plasma cutting.
  • Full ASME SB-575, SB-574, SB-622 certification for Code construction.
  • PMI (XRF) on every piece as standard practice.
  • Technical consultation on grade selection, environment compatibility, and fabrication.
  • Emergency supply for maintenance and shutdown requirements.
  • Competitive pricing with same-day quotation response.

Contact MWalloys today to discuss your Hastelloy requirements. Submit a technical inquiry through our website or speak directly with our alloy selection engineering team for application-specific recommendations and same-day quotations.

Verified and Authoritative Sources

  1. Haynes International – Hastelloy C-276 Alloy Technical Brochure (H-2002E); Hastelloy C-22 Alloy Technical Brochure (H-2019C); Hastelloy B-3 Alloy Technical Brochure (H-2063).
  2. ASTM International – ASTM B575: Standard Specification for Low-Carbon Nickel-Chromium-Molybdenum Alloy Plate, Sheet, and Strip.
  3. ASTM International – ASTM B574: Standard Specification for Low-Carbon Nickel-Molybdenum-Chromium Alloy Rod.
  4. ASTM International – ASTM B622: Standard Specification for Seamless Nickel and Nickel-Cobalt Alloy Pipe and Tube.
  5. ASME Boiler and Pressure Vessel Code, Section II, Part B – Nonferrous Material Specifications. American Society of Mechanical Engineers.
  6. ASME Boiler and Pressure Vessel Code, Section II, Part D – Properties (Allowable Stresses). American Society of Mechanical Engineers.
  7. NACE International (AMPP) – NACE MR0175 / ISO 15156: Petroleum and Natural Gas Industries – Materials for Use in H₂S-Containing Environments. Parts 1, 2, and 3.
  8. AWS A5.14 / ASME SFA-5.14 – Specification for Nickel and Nickel-Alloy Bare Welding Electrodes and Rods. American Welding Society.
  9. ASM International – ASM Handbook, Volume 13A: Corrosion: Fundamentals, Testing, and Protection. ASM International. ISBN 978-0-87170-705-5.
  10. ASM International – ASM Handbook, Volume 13B: Corrosion: Materials. ASM International. ISBN 978-0-87170-707-9.
  11. Schweitzer, P.A. – Corrosion Engineering Handbook, 2nd Edition. CRC Press. ISBN 978-0-8493-8234-2.
  12. Fontana, M.G. – Corrosion Engineering, 3rd Edition. McGraw-Hill. ISBN 978-0-07-021463-7.
  13. ASTM International – ASTM G28: Standard Test Methods for Detecting Susceptibility to Intergranular Corrosion in Wrought, Nickel-Rich, Chromium-Bearing Alloys.
  14. EN 10204:2004 – Metallic Products: Types of Inspection Documents. European Committee for Standardization, Brussels.
  15. Crook, P. – "Hastelloy Corrosion-Resistant Alloys: Principles and Practices." Haynes International Technical Paper, 1994.
  16. ISO 15156-3:2020 – Petroleum and Natural Gas Industries – Materials for Use in H₂S-Containing Environments – Part 3: Cracking-Resistant CRAs and Other Alloys. ISO, Geneva.

Statement: This article was published after being reviewed by MWalloys technical expert Ethan Li.

MWalloys Engineer ETHAN LI

ETHAN LI

Global Solutions Director | MWalloys

Ethan Li is the Chief Engineer at MWalloys, a position he has held since 2009. Born in 1984, he graduated with a Bachelor of Engineering in Materials Science from Shanghai Jiao Tong University in 2006, then earned his Master of Engineering in Materials Engineering from Purdue University, West Lafayette, in 2008. Over the past fifteen years at MWalloys, Ethan has led the development of advanced alloy formulations, managed cross‑disciplinary R&D teams, and implemented rigorous quality and process improvements that support the company’s global growth. Outside the lab, he maintains an active lifestyle as an avid runner and cyclist and enjoys exploring new destinations with his family.

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